Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Slide at 39:29

Asymmetric Radical Multicomponent Couplings via Sensitization
Models for the divergent enantioselectivity of different catalytic systems
2.79
H-H=3.18
2.80
H-H=2.10
(S,S)-L8
(R)-Prod
major product
(S)-Prod
minor product
F-TS-GR
B+3F
Triplet Ni(II)
F-TS-G$
Erol=0.0
Ere==2.0
Chem, 2023, 9, 154-169.

References

1.
X. Li et al. (2022) Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis. Chem

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Summary (AI generated)

With the optimal man, we can easily use tools to simplify photo copies. This allows us to achieve the Z ester divergence and the initial selective carbon calculations of one phosphate. By delivering these already phosphate with a high standard selectivity and initial selectivity control.