Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:08:31
Exchange between Co-Si and Co-H SiHPh int3(triplet) TS4(triplet) -7.6 -7.3 int2(CSS) Ph2SiH2 -15.1 MECP8 -15.9 int1 (triplet) -16.6 20.3 -22.7 TS4(CSS) -21.8 21.5 int2(triplet) int3(CSS) int1(OSS) SiHPh SiHPh2 Triplet Co-Si species vs Open-Shell Singlet Co-H Computational studies were conducted by Prof. Xin Hong, to be submitted
Share slide
Summary (AI generated)

The spin state of the intermediate changes frequently, allowing the reaction to occur. Previously, a high and anti-selective reaction was achieved using a mixture with a Chating group. Our search involves summarization, but it should also consider the thermodynamic disadvantage.