Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:14:31
Discussion of the mechanism on hydrosilane as a hydride transfer Dihydride Species: Addition and RE to generate Low Valent M Monohydride Species: Addition and Protonolysis to generate High Valent M H MOX Matathesis with Hydrogen to Generate M-H Species H M H + M-H Hydride Shuttle for Metathesis with Hydrogen to Generate M-H Species I I + M-Z Yonggui Zhou, The 7th Summer School of Chiral Material Science 2018 Hefei
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References
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    Yonggui Zhou, The 7th Summer School of Chiral Material Science 2018 Hefei
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Summary (AI generated)

We found the mechanism quite interesting and discussed it with Professor Yong Guizhou in the IC P. He suggested using hydrate the shuttle to code the hydro cylinder, which plays a role in generating the active metal species. People often ask if we need to use the arrow to achieve high energy selectivity, including the 11 die arrow and 11 dot RQ sub to the elephant. One of my undergraduate students should be appreciated for doing a lot of screening as an undergraduate and finding that a larger ligand could increase selectivity and reactivity.