Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:15:17
Iron (I) hydride-catalyzed AH of 1,1-dialkyl - alkenes iron catalyst additives (balloon) CHPh2 Fe-N ipPh2HC 8-IIQ-FeCl2 8-l'IQFeCl2 8-OIQ+FeCl2 32% conv., 70% ee >99% conv., 92% ee 42% conv., 54% ee Lu, Z. et al to be submitted.
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References
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    Lu, Z. et al to be submitted.
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Summary (AI generated)

The product can be guided with full conversion and 92% ee. Compared to the metal, one species has a different coordination model than the metal two species.