Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 1:29:26
Cp*Rh( (III) Catalysts for C-H Activation [Cp*RhCl2]2 (1 mol %) CO2H Cu(OAc)2, air DMF, 100 °C Satoh, T.; Miura, M. et al. Org. Lett. 2007, 9, 1407. Rh is expensive: ca. 140 USD per gram (2023/9) Reviews : Sato & Miura: Chem. Eur. J. 2010, 16, 11212. Glorius et al.: Adv. Synth. Catal. 2014, 356, 1443. Li et al.: Acc. Chem. Res. 2015, 48, 1007.
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References
  • 1.
    K. Ueura et al. (2007) An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage:  Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air. Organic Letters
  • 2.
    T. Satoh and M. Miura (2010) Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis. Chemistry – A European Journal
  • 3.
    N. Kuhl et al. (2014) Formal SN‐Type Reactions in Rhodium(III)‐Catalyzed CH Bond Activation. Advanced Synthesis & Catalysis
  • 4.
    G. Song and X. Li (2015) Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes. Accounts of Chemical Research
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