Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 1:31:44
Chiral Cp Complexes Me Rh Cramer (2012, 2013) (2016, 2021) CO2R3 Waldmann Perekalin Antonchick Blakey (2017) (2018) (2020) Review : Cramer, N. et al. Angew. Chem. Int. Ed. 2021, 60, 13198. Other complexes : Ward, T. R.; Rovis, T. et al. Science 2012, 338, 500. Wang, J. et al. Angew. Chem. Int. Ed. 2020, 59, 22436.
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References
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    G. Li et al. (2020) Chiral Bicyclo[2.2.2]octane‐Fused CpRh Complexes: Synthesis and Potential Use in Asymmetric C−H Activation. Angewandte Chemie International Edition
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    B. Ye and N. Cramer (2012) Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C–H Functionalization. Science
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    E. A. Trifonova et al. (2018) A Planar‐Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones. Angewandte Chemie International Edition
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Summary (AI generated)

Many other groups have developed their own Cairo cp rhodium, iridium, and cobalt catalysts after this work. These catalysts have been successfully applied in various cat functionalization reactions involving cobalt. In 2019, Gramas group reported the use of these types of Co CP cobalt catalysts. They also provided the catalyst for Enio activation via C one activation.