Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 1:43:38
Proposed Catalytic Cycle NHBz Cp*/Bu [Co] [Co]-O s-[Co] s-[Co]-O
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Summary (AI generated)

The reaction mechanism involves the coordination of t to cobalt and carboxylate, creating the V ID mechanism to form an intermediate metal cycle. This process should be irreversible. The dioxins, metal, and CO2 are released during this step, with some conversion to Nitroso formation to form a bond with the intermediate. Protonation then produces the final product and regenerates the catalyst.