Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 1:32:42
Chiral CpCo Catalysts chiral CpCo cat. Ozols, K.; Jang, Y. S.; Cramer, N. J. Am. Chem. Soc. 2019, 141, 5675. Ozols, K.; Onodera, S.; Wozniak, L.; Cramer, N. Angew. Chem. Int. Ed. 2020, 60, 655. Enantio-control after C-H Activation
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References
  • 1.
    K. Ozols et al. (2019) Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C–H Functionalizations. Journal of the American Chemical Society
  • 2.
    K. Ozols et al. (2020) Cobalt(III)‐Catalyzed Enantioselective Intermolecular Carboamination by C−H Functionalization. Angewandte Chemie International Edition
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Summary (AI generated)

In these cases, the catalyst exhibits activities after C activation. Our strategy for insertion is slightly different.