Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:21:34
Part III: Ligand Controlled Programmed Sequential Reactions of Alkynes Combinatorial catalysis: regio-divergent synthesis of bissilanes [Si] [Si] [Si] [Si] [OIPCo] H-[Si] [Xantphos*Co] [Si] [Si] H-[Si] [Si] [Si] NaBHEt3 Atom and pot economy Controllable regioselectivity Catalytic synthetic methods Asymmetric catalysis Realized double hydrosilylation of terminal alkynes et al Angew. Chem. Int. Ed. 2021, 60, 22454; 2023, 62, e202215029; Chem 2019, 5, 881; Chin. J. Chem. 2019, 37, 457; computational studies: Prof. Xin Hong; materials: Prof. Xinghong Zhang
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References
  • 1.
    Z. Cheng et al. (2021) Regio‐controllable Cobalt‐Catalyzed Sequential Hydrosilylation/Hydroboration of Arylacetylenes. Angewandte Chemie International Edition
  • 2.
    Z. Cheng et al. (2022) Cobalt‐Catalyzed Regiodivergent Double Hydrosilylation of Arylacetylenes. Angewandte Chemie International Edition
  • 3.
    L. Gao et al. (2019) A Novel One-Pot Synthesis of Poly(Propylene Carbonate) Containing Cross-Linked Networks by Copolymerization of Carbon Dioxide, Propylene Oxide, Maleic Anhydride, and Furfuryl Glycidyl Ether. Polymers
  • 4.
    Z. Cheng et al. (2019) Highly Regioselective Sequential 1,1‐Dihydrosilylation of Terminal Aliphatic Alkynes with Primary Silanes. Chinese Journal of Chemistry
  • 5.
    Prof. Xin Hong
  • 6.
    Prof. Xinghong Zhang
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Summary (AI generated)

One example is shown to demonstrate how combining the phosphine ligand with the Nitro ligand can result in Beyle selectivity. The full product can be obtained using different methods of separation.