Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:23:40
Applications by other research groups (Mo) (Co) OIPCoBr2 Zn 4-tBu- OIPMo(COD) then CbzCI Uyeda, C et al J Am Chem Soc. 2023 10.1021/jacs.3c01949 Chirik, P. J. et al I Am. Chem Soc. 2022 144, 11203 R1 H, NBn2, R2 = Bn, tBu (Co) hetero(arene) hydrogenation activity. Molybdenum complexes Z=0,NR, S of mixed OIP type ligands pioneered by Lu and co- OIPCoCl2 R2, workers were therefore targeted. Metalation of the OIP ArSiH3 SiH2Ar ligands proceeded in high yield, and a small library NaHBEt, (OIP)MoCl, complexes was prepared. Reduction of each of Marek I. et al Org Lett 2020. 22. 4914 (Cu) (Co) Cu(l) Co(salen) Bpin R2-X HBpin OPPA, base OPPA, Mn Liu, X et al Angew Chem Int Ed. 2023 62. e202218523 ZPPA Zhao, W et al Angew Chem Int. Ed. 2023 62. e202306248 R = H, Me (Pd) Z(V) IPOPAPdCI IPOPAVOCI Et2AI2Cl3, CCICOEt R'=R2=H; or R'=H, R2=CH,=CH. Bai, C.-X. et al Polymer 2019 172, 196. Bai, C.-X et al Dalton Trans. 2021. 50, 16067 IPOPA
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References
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    P. Viereck et al. (2022) Molybdenum-Catalyzed Asymmetric Hydrogenation of Fused Arenes and Heteroarenes. Journal of the American Chemical Society
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    L. Dian and I. Marek (2020) Cobalt-Catalyzed Diastereoselective and Enantioselective Hydrosilylation of Achiral Cyclopropenes. Organic Letters
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    H. Zhou et al. (2023) Copper‐Catalyzed Chemo‐ and Enantioselective Radical 1,2‐Carbophosphonylation of Styrenes. Angewandte Chemie International Edition
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    M. Zhang et al. (2023) Cobalt‐Catalyzed Asymmetric Remote Borylation of Alkyl Halides. Angewandte Chemie International Edition
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    J. He et al. (2019) High Tg and thermostable phytic Acid−Cured polynorbornene-based polymer by a Palladium(Ⅱ) complex bearing iminophenyl oxazolinylphenylamines ligand. Polymer
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    R. Wu et al. (2021) Thermally stable vanadium complexes supported by the iminophenyl oxazolinylphenylamine ligands: synthesis, characterization and application for ethylene (co-)polymerization. Dalton Transactions
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Summary (AI generated)

I want to thank my students, collaborators, and the funding support. I also want to thank the audience and am happy to answer any questions. Thank you, that's all.