Base-Metal Catalysis - presented by Prof. Lingling Chu and Assoc. Prof. Ming Joo Koh and Prof. Zhan Lu and Assoc. Prof. Tatsuhiko Yoshino and Prof. Naohiko Yoshikai

Base-Metal Catalysis

Lingling Chu, Ming Joo Koh, Zhan Lu and Tatsuhiko Yoshino

Prof. Lingling ChuAssoc. Prof. Ming Joo KohAssoc. Prof. Tatsuhiko YoshinoProf. Zhan Lu
Slide at 2:11:20
Part II: Ligands regulate the coordination modes and valence states of metal:
Cobalt (I) species
Iron (I) species
OIP.Co-H
OIPFe-H
d8, rigid coordination mode
d7, rigid coordination mode
reversible isomerization,
hydrogenation, hydroboration,
hydrosilylation Formation of primary
carbon cobalt species
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Summary (AI generated)

In our previous discussion, we talked about the cobalt species. Now, let's consider the iron species. This species differs from the cobalt species. In our previous study, we successfully achieved the IOC catalyzed Asymmetric hydration, but the Hydrosport was unsuccessful. For example, reports of Asymmetric reduction reactions using iron catalysts have shown that even with pressure metals, the selectivity is not very high.

We are grateful to Professor Nikonov for highlighting our work and giving us credit. He referred to this catalyst as "lo Carol."